But all I know mate is you have a Asus 1150 Motherboard
I don't not run any of that crap Jer I set all bios manual, it is just more bloat for mine.
You can make a movie and gaming profile in bios, I don't nor ever liked OS/software overclocking other then for Benchtests.
As long as my PC can run full load 24/7 at decent temps at a given ambient temp.
I going to assume the H100i has not arrived, that will solve 1/2 your problem.
1. MAKE SURE you clean Processor properly of thermal tape and do not scratch it for goodness sakes.
I used artic cleaner for decade
http://www.newegg.com/Product/Product.aspx?Item=N82E16835100010
2. Corsair H100i comes with pre-fitted TM (thermal material)
Make sure you do not bump or scratch that either.
Drop it on the lugs gentle and even, tighten even, you good to go.
After you re-check full load Processor temps in Prime, 3DMark and rF2 you can worry about the GPU.